Heinz Koch

Heinz Koch

Emeritus Professor, Department of Chemistry
Faculty, School of Humanities and Sciences

Publications

  H. F. Koch, G. Lodder, J. G. Koch, D. J. Bogdan, G. H. Brown, C. A. Carlson, A. B. Dean, R. Hage, P. Han, J.C. P Hopman, L. A, James, P. M. Knape, E. C. Roos, M. L. Sardia, R. A. Sawyer, B. O. Scott, C. A. Testa, III, and S. D. Wickham, "Use of Kinetic Isotope Effects in Mechanism Studies: 5. Isotope and Element Effects Associated with Hydron-Transfer Steps During Alkoxide-Promoted Dehydrohalogenations:" J. Am. Soc. 1997, 118, 9965

H. F. Koch, M. Mishima and H. Zuilhof, "Proton Transfer Between Carbon Acids and Methoxide: Studies in Methanol, the Gas Phase and Ab Iniotio MO Calculations." Ber. Bunsenges. Phys. Chem. 1998, 102, 567-572

H. F. Koch, J. C. Biffinger, M. Mishima, Mustanir and G. Lodder, "Comparison of ΔG0Acid,  Gas Phase, and Kinetic Acidities Measured in Methanolic Sodium Methoxide:" J. Phys. Org. Chem. 1998, 11, 614-617.

H. F. Koch, W. C. Pomerantz, E. L. Ruggles, M. van Laren and A-M van Roon, "Comparing Isotope Effects and Rates for Methanolic Sodium Methoxide Reactions of 9-R-Fluorene to those for p-CF3C6H4CHClR (R = CH2Cl, CH2F, and CF3)”  Collect. Czech. Chem. Commun., 2002, 67, 1505-1516.

H. F. Koch, "The Role of an Internal-Return Mechanism on Measured Isotope Effects" in "Isotope Effects in Chemistry and Biology" ed. A. Kohen and H-H. Limbach, CRC, NYC, 2006.

V. F. DeTuri, H. F. Koch, J. G. Koch, G. Lodder, M. Mishima, H. Zuilhof, N. M. Abrams, C. E. Anders, J. C. Biffinger, P. Han, A. R. Kurland, J. M. Nichols, A. M. Ruminski, P. R. Smith, and K. D. Vasey.  "Comparison of Gas-Phase Acids with their Rates of Hydron Exchange in Methanolc Methoxide."  J. Phys. Org. Chem. 2006, 19, 308-317.

Mustanir, M. Matsuoka, M. Mishima and H. F. Koch, "Stability of Complexes of Phenylacetylides and Benzyl Alkoxides with Methanol in the Gas Phase.  Acid-base Correlation in the Ionic Hydrogen Bond Strength."  Bull. Chem Soc. Jpn. 2006, 79, 1118-1125.

H. F. Koch, "Formation of Hydrogen-bonded Carbanions as Intermediates in Hydrogen Transfer between Carbon and Oxygen" in "Handbook of Hydrogen Transfer" ed. R. L. Schowen, Wiley-VCH, 2006.

Heinz F. Koch1,*, Judith G. Koch1, Masaaki Mishima2, Pasquale Iacono1, and Nicole W. Wedgwood1 Z. Phys. Chem. 222 (2008) 1175-1184 / DOI 10.1524/zpch.2008.5381 © by Oldenbourg Wissenschaftsverlag, München, "The Competition of the Loss of a Beta Fluoride and Hydron Transfer Between Carbon and Oxygen During Exchange and Elimination Reactions".

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